Selective methane chemiresistive detection using MWCNTs array decorated by metal organic framework layer

dc.contributor.authorZabelin, Denis
dc.contributor.authorZabelina, Anna
dc.contributor.authorGuselnikova, Olga
dc.contributor.authorMiliutina, Elena
dc.contributor.authorKolská, Zdeňka
dc.contributor.authorŠtulík, Jiří
dc.contributor.authorPolanský, Radek
dc.contributor.authorElashnikov, Roman
dc.contributor.authorKalachyova, Evgeniia
dc.contributor.authorŠvorčík, Václav
dc.contributor.authorLyutakov, Oleksiy
dc.date.accessioned2023-08-14T10:00:18Z
dc.date.available2023-08-14T10:00:18Z
dc.date.issued2023
dc.description.abstract-translatedMethane as a main component of natural gas, but simultaneously an explosive compound with pronounced negative environmental impact. Therefore, methane should be detected with high precision and reliability. However, the inertness and non-polar nature of methane is limiting its simple detection (e.g., by a chemiresistive approach) living a gap in sensing solution. In this paper, we propose a selective chemiresistive methane sensor consisting of abundant carbon materials (multi-walled carbon nanotubes - MWCNTs) with a metal-organic framework (PCN-14). The sensor is based on decorating a non-ordered array of MWCNTs with PCN-14, which is known to have high selectivity towards methane. The methane molecules are selectively entrapped by PCN-14 pores, which significantly affect the resistance of created hybrid materials. As a result, we could detect methane under air pressure and at room temperature, with a negligible false response from other interfering gases or moisture (except hydrogen or ethane). Despite its extreme simplicity, our chemiresistive sensor does not require chemical reaction or material-destructive binding/oxidation of methane. Therefore, long operation time and sensor stability were expected and experimentally confirmed. Finally, the initial resistance of MWCNTs-PСN-14 hybrid materials was adjusted to be measurable by a portative multimeter range, which makes our approach very simple and technically undemanding.en
dc.format
dc.format8 s.cs
dc.format.mimetypeapplication/pdf
dc.identifier.citationZABELIN, D. ZABELINA, A. GUSELNIKOVA, O. MILIUTINA, E. KOLSKÁ, Z. ŠTULÍK, J. POLANSKÝ, R. ELASHNIKOV, R. KALACHYOVA, E. ŠVORČÍK, V. LYUTAKOV, O. Selective methane chemiresistive detection using MWCNTs array decorated by metal organic framework layer. Surfaces and Interfaces, 2023, roč. 40, č. August 2023, s. nestránkováno. ISSN: 2468-0230cs
dc.identifier.document-number1032795200001
dc.identifier.doi10.1016/j.surfin.2023.103105
dc.identifier.issn2468-0230
dc.identifier.obd43939918
dc.identifier.uri2-s2.0-85163955915
dc.identifier.urihttp://hdl.handle.net/11025/53861
dc.language.iso
dc.language.isoenen
dc.project.IDGA20-03913S/Organické senzory plynů - nové struktury, jejich vlastnosti a funkcecs
dc.publisherElsevieren
dc.relation.ispartofseriesSurfaces and Interfacesen
dc.rightsPlný text je přístupný v rámci univerzity přihlášeným uživatelůmcs
dc.rights© Elsevieren
dc.rights.accessrestrictedAccessen
dc.subject.translatedmethane detectionen
dc.subject.translatedmulti-walled carbon nanotubesen
dc.subject.translatedmetal organic frameworken
dc.subject.translatedchemiresistive materialsen
dc.titleSelective methane chemiresistive detection using MWCNTs array decorated by metal organic framework layeren
dc.typečlánekcs
dc.typearticleen
dc.type.status
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen

Files

Original bundle
Showing 1 - 1 out of 1 results
No Thumbnail Available
Name:
Stulik_1-s2.0-S2468023023004753-main.pdf
Size:
7.77 MB
Format:
Adobe Portable Document Format
OPEN License Selector